Jade

Two different minerals are known as jade. These are jadeite and nephrite. Jadeite is an aluminosilicate mineral where the charge of the aluminosilicate framework is balanced by sodium ions, while nephrite is a silicate mineral where the cations are calcium and magnesium. In jadeite, the SiO4 tetrahedra are share an oygen atom with an adjacent SiO4 group to produce into one-dimensional chains. In nephrite, the SiO4 unit are first linked into -[SiO]6- rings that are then fused into one-dimensional chains. Trace transition metal ions such as iron and chromium are responsible for the color. Jade can range from white to light green to dark greend, but may also occur in yellows, brown, black, reds, pinks and violets. Jadeite is slightly harder with a Mohs harness of 6.5 to 7.0, while that of nephrite is 6.0 to 6.5.

The crystal lattice of jadeite, NaAlSi2O6.
The crystal lattice of jadeite showing only the silicate chains.
The crystal lattice of jadeite showing the silicate chains with aluminum atoms attached.
The crystal lattice of nephrite, Ca2(Mg,Fe)5Si8O22(OH)2. Note that the Fe and Mg occupy the same site in the crystal lattice so only the Mg atoms are shown.
The silicate portrion of the nephrite lattice. The SiO4 tetrahedra are linked into six-membered rings, which are then connected into one-dimensional rows.



Jmol Colors Element colors for the figures below: http://jmol.sourceforge.net/jscolors/ The color codes used for structures on this page.



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